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The Resource Palladium-Catalyzed Coupling Reactions

Palladium-Catalyzed Coupling Reactions

Creator
Summary
This handbook and ready reference brings together all significant issues of practical importance for interested readers in one single volume. While covering homogeneous and heterogeneous catalysis, the text is unique in focusing on such important aspects as using different reaction media, microwave techniques or catalyst recycling. It also provides a comprehensive treatment of modern-day coupling reactions and emphasizes those topics that show potential for future development, such as continuous flow systems, water as a reaction medium, and catalyst immobilization, among others. With i
Language
eng
Work
Publication
Edition
2nd ed.
Extent
1 online resource (533 pages)
Note
3.2 General Considerations Concerning Magnetic Particles as Catalyst Supports
Contents
  • Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Contents; Foreword; Preface; List of Contributors; 1 Palladium-Catalyzed Cross-Coupling Reactions -- A General Introduction; 1.1 Introduction; 1.1.1 Historical Reflection; 1.1.2 Characteristics, Recent Developments, and Progress; 1.1.3 Literature Reviews and Organization of the Chapter; 1.2 Carbon-Carbon Cross-Coupling Reactions Catalyzed by Palladium; 1.2.1 Classification and Overview; 1.2.2 Common Mechanistic Features of Cross-Coupling Reactions and Reactivity of the Substrates
  • 1.2.2.1 Choice of the Carbon Electrophile1.2.2.2 Choice of the Carbon Nucleophile -- What Makes the Difference?; 1.3 The Catalysts; 1.3.1 The Particular Features of Palladium; 1.3.2 Classes of Palladium Catalysts Applied to Cross-Coupling Reactions; 1.3.2.1 Ligands and Palladium Complexes -- Homogeneous Systems; 1.3.2.2 Immobilized or Supported Palladium Complexes and Particles -- Heterogeneous Systems; 1.3.2.3 Palladium Colloids and (Nonsupported) Nanoparticles; 1.3.2.4 Activity of Heterogeneous Catalysts; 1.4 Mechanistic Aspects
  • 1.4.1 General Mechanism of C C Cross-Coupling and Heck Reactions with Homogeneous Catalyst Precursors1.4.2 Models for Heck and Suzuki Reactions with Supported Pd Precursors; 1.4.3 Recent Results on the Reaction Mechanism and the Nature of the Active Pd Species; 1.4.3.1 Observation of Intermediates in Homogeneous Catalysis by Electrochemical Methods; 1.4.3.2 The Question of Pd Leaching; 1.4.3.3 Selectivity Pattern; 1.4.3.4 In Situ Observation by Spectroscopic Methods; 1.4.3.5 Immobilized Pd Pincer Complexes; 1.4.3.6 Palladium Bulk Materials (Pd Foil, Wire, Sponge) as Catalyst
  • 1.5 Future ChallengesAbbreviations; References; 2 High-Turnover Heterogeneous Palladium Catalysts in Coupling Reactions: the Case of Pd Loaded on Dealuminated Y Zeolites; 2.1 Introduction; 2.2 Various Methodologies to Afford High Turnover Numbers Over Supported Pd Catalysts; 2.3 Structure and Characteristics of Ultrastable Y Zeolites; 2.4 Suzuki-Miyaura Reactions Catalyzed by Pd/USY; 2.4.1 Catalytic Performance of Pd/USY; 2.4.2 Pd Leaching from Pd/USY; 2.4.3 Selectivity in the Homocoupling Reactions; 2.4.4 Characterization of the Active Pd Species by X-Ray Absorption Spectroscopy
  • 2.4.5 A Suggested Mechanism for the Formation of Active Pd Species in Suzuki-Miyaura Coupling Reactions2.5 Catalytic Performance of Pd/USY in Mizoroki-Heck Reactions; 2.5.1 Effect of H2 Bubbling on the Catalytic Reactions of Pd/USY; 2.5.2 Catalytic Reactions Using Chlorobenzene Derivatives; 2.5.3 Characterization of the Pd Species by X-Ray Absorption Spectroscopy; 2.6 Conclusion and Perspective; Abbreviations; References; 3 Palladium-Catalyzed Coupling Reactions with Magnetically Separable Nanocatalysts; 3.1 Introduction
Isbn
9783527648306
Instance
Label
Palladium-Catalyzed Coupling Reactions
Title
Palladium-Catalyzed Coupling Reactions
Creator
Subject
Language
eng
Summary
This handbook and ready reference brings together all significant issues of practical importance for interested readers in one single volume. While covering homogeneous and heterogeneous catalysis, the text is unique in focusing on such important aspects as using different reaction media, microwave techniques or catalyst recycling. It also provides a comprehensive treatment of modern-day coupling reactions and emphasizes those topics that show potential for future development, such as continuous flow systems, water as a reaction medium, and catalyst immobilization, among others. With i
Member of
Cataloging source
EBLCP
http://library.link/vocab/creatorName
Moln?r,?rp?d
Dewey number
541.395
Index
no index present
LC call number
QD505
Literary form
non fiction
Nature of contents
dictionaries
http://library.link/vocab/subjectName
  • Couplings
  • Catalysis
  • Catalysis
  • Couplings
Label
Palladium-Catalyzed Coupling Reactions
Instantiates
Publication
Note
3.2 General Considerations Concerning Magnetic Particles as Catalyst Supports
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
  • Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Contents; Foreword; Preface; List of Contributors; 1 Palladium-Catalyzed Cross-Coupling Reactions -- A General Introduction; 1.1 Introduction; 1.1.1 Historical Reflection; 1.1.2 Characteristics, Recent Developments, and Progress; 1.1.3 Literature Reviews and Organization of the Chapter; 1.2 Carbon-Carbon Cross-Coupling Reactions Catalyzed by Palladium; 1.2.1 Classification and Overview; 1.2.2 Common Mechanistic Features of Cross-Coupling Reactions and Reactivity of the Substrates
  • 1.2.2.1 Choice of the Carbon Electrophile1.2.2.2 Choice of the Carbon Nucleophile -- What Makes the Difference?; 1.3 The Catalysts; 1.3.1 The Particular Features of Palladium; 1.3.2 Classes of Palladium Catalysts Applied to Cross-Coupling Reactions; 1.3.2.1 Ligands and Palladium Complexes -- Homogeneous Systems; 1.3.2.2 Immobilized or Supported Palladium Complexes and Particles -- Heterogeneous Systems; 1.3.2.3 Palladium Colloids and (Nonsupported) Nanoparticles; 1.3.2.4 Activity of Heterogeneous Catalysts; 1.4 Mechanistic Aspects
  • 1.4.1 General Mechanism of C C Cross-Coupling and Heck Reactions with Homogeneous Catalyst Precursors1.4.2 Models for Heck and Suzuki Reactions with Supported Pd Precursors; 1.4.3 Recent Results on the Reaction Mechanism and the Nature of the Active Pd Species; 1.4.3.1 Observation of Intermediates in Homogeneous Catalysis by Electrochemical Methods; 1.4.3.2 The Question of Pd Leaching; 1.4.3.3 Selectivity Pattern; 1.4.3.4 In Situ Observation by Spectroscopic Methods; 1.4.3.5 Immobilized Pd Pincer Complexes; 1.4.3.6 Palladium Bulk Materials (Pd Foil, Wire, Sponge) as Catalyst
  • 1.5 Future ChallengesAbbreviations; References; 2 High-Turnover Heterogeneous Palladium Catalysts in Coupling Reactions: the Case of Pd Loaded on Dealuminated Y Zeolites; 2.1 Introduction; 2.2 Various Methodologies to Afford High Turnover Numbers Over Supported Pd Catalysts; 2.3 Structure and Characteristics of Ultrastable Y Zeolites; 2.4 Suzuki-Miyaura Reactions Catalyzed by Pd/USY; 2.4.1 Catalytic Performance of Pd/USY; 2.4.2 Pd Leaching from Pd/USY; 2.4.3 Selectivity in the Homocoupling Reactions; 2.4.4 Characterization of the Active Pd Species by X-Ray Absorption Spectroscopy
  • 2.4.5 A Suggested Mechanism for the Formation of Active Pd Species in Suzuki-Miyaura Coupling Reactions2.5 Catalytic Performance of Pd/USY in Mizoroki-Heck Reactions; 2.5.1 Effect of H2 Bubbling on the Catalytic Reactions of Pd/USY; 2.5.2 Catalytic Reactions Using Chlorobenzene Derivatives; 2.5.3 Characterization of the Pd Species by X-Ray Absorption Spectroscopy; 2.6 Conclusion and Perspective; Abbreviations; References; 3 Palladium-Catalyzed Coupling Reactions with Magnetically Separable Nanocatalysts; 3.1 Introduction
Control code
830165269
Dimensions
unknown
Edition
2nd ed.
Extent
1 online resource (533 pages)
Form of item
online
Isbn
9783527648306
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Specific material designation
remote
System control number
(OCoLC)830165269
Label
Palladium-Catalyzed Coupling Reactions
Publication
Note
3.2 General Considerations Concerning Magnetic Particles as Catalyst Supports
Carrier category
online resource
Carrier category code
  • cr
Carrier MARC source
rdacarrier
Content category
text
Content type code
  • txt
Content type MARC source
rdacontent
Contents
  • Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Contents; Foreword; Preface; List of Contributors; 1 Palladium-Catalyzed Cross-Coupling Reactions -- A General Introduction; 1.1 Introduction; 1.1.1 Historical Reflection; 1.1.2 Characteristics, Recent Developments, and Progress; 1.1.3 Literature Reviews and Organization of the Chapter; 1.2 Carbon-Carbon Cross-Coupling Reactions Catalyzed by Palladium; 1.2.1 Classification and Overview; 1.2.2 Common Mechanistic Features of Cross-Coupling Reactions and Reactivity of the Substrates
  • 1.2.2.1 Choice of the Carbon Electrophile1.2.2.2 Choice of the Carbon Nucleophile -- What Makes the Difference?; 1.3 The Catalysts; 1.3.1 The Particular Features of Palladium; 1.3.2 Classes of Palladium Catalysts Applied to Cross-Coupling Reactions; 1.3.2.1 Ligands and Palladium Complexes -- Homogeneous Systems; 1.3.2.2 Immobilized or Supported Palladium Complexes and Particles -- Heterogeneous Systems; 1.3.2.3 Palladium Colloids and (Nonsupported) Nanoparticles; 1.3.2.4 Activity of Heterogeneous Catalysts; 1.4 Mechanistic Aspects
  • 1.4.1 General Mechanism of C C Cross-Coupling and Heck Reactions with Homogeneous Catalyst Precursors1.4.2 Models for Heck and Suzuki Reactions with Supported Pd Precursors; 1.4.3 Recent Results on the Reaction Mechanism and the Nature of the Active Pd Species; 1.4.3.1 Observation of Intermediates in Homogeneous Catalysis by Electrochemical Methods; 1.4.3.2 The Question of Pd Leaching; 1.4.3.3 Selectivity Pattern; 1.4.3.4 In Situ Observation by Spectroscopic Methods; 1.4.3.5 Immobilized Pd Pincer Complexes; 1.4.3.6 Palladium Bulk Materials (Pd Foil, Wire, Sponge) as Catalyst
  • 1.5 Future ChallengesAbbreviations; References; 2 High-Turnover Heterogeneous Palladium Catalysts in Coupling Reactions: the Case of Pd Loaded on Dealuminated Y Zeolites; 2.1 Introduction; 2.2 Various Methodologies to Afford High Turnover Numbers Over Supported Pd Catalysts; 2.3 Structure and Characteristics of Ultrastable Y Zeolites; 2.4 Suzuki-Miyaura Reactions Catalyzed by Pd/USY; 2.4.1 Catalytic Performance of Pd/USY; 2.4.2 Pd Leaching from Pd/USY; 2.4.3 Selectivity in the Homocoupling Reactions; 2.4.4 Characterization of the Active Pd Species by X-Ray Absorption Spectroscopy
  • 2.4.5 A Suggested Mechanism for the Formation of Active Pd Species in Suzuki-Miyaura Coupling Reactions2.5 Catalytic Performance of Pd/USY in Mizoroki-Heck Reactions; 2.5.1 Effect of H2 Bubbling on the Catalytic Reactions of Pd/USY; 2.5.2 Catalytic Reactions Using Chlorobenzene Derivatives; 2.5.3 Characterization of the Pd Species by X-Ray Absorption Spectroscopy; 2.6 Conclusion and Perspective; Abbreviations; References; 3 Palladium-Catalyzed Coupling Reactions with Magnetically Separable Nanocatalysts; 3.1 Introduction
Control code
830165269
Dimensions
unknown
Edition
2nd ed.
Extent
1 online resource (533 pages)
Form of item
online
Isbn
9783527648306
Media category
computer
Media MARC source
rdamedia
Media type code
  • c
Specific material designation
remote
System control number
(OCoLC)830165269

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