The Resource The effect of supercritical water on crude glycerin solution, by Jared Scott Bouquet
The effect of supercritical water on crude glycerin solution, by Jared Scott Bouquet
Resource Information
The item The effect of supercritical water on crude glycerin solution, by Jared Scott Bouquet represents a specific, individual, material embodiment of a distinct intellectual or artistic creation found in Missouri University of Science & Technology Library.This item is available to borrow from 1 library branch.
Resource Information
The item The effect of supercritical water on crude glycerin solution, by Jared Scott Bouquet represents a specific, individual, material embodiment of a distinct intellectual or artistic creation found in Missouri University of Science & Technology Library.
This item is available to borrow from 1 library branch.
- Summary
- "Crude glycerin solution, a principal byproduct of the conventional biodiesel process, was reacted in supercritical water using a specially designed Haynes® Alloy 282 reactor system for the production of hydrogen rich syngas. The effects of temperature, pressure, water-to-carbon molar ratio, reactor residence time, and glycerin-to-methanol weight ratio on the extent of carbon gasification and gas composition were explored. Based on the results, the extent and selectivity of reactions that concurrently occur when methanol and glycerin are in the presence of supercritical water were analyzed. A decomposition reaction pathway for glycerin conversion to syngas was hypothesized, and then utilizing the results of the crude glycerin solution experiments, as well as experiments using pure methanol and pure glycerin with supercritical water, the hypothesized decomposition pathway was evaluated. Also an empirical equation was formulated to predict the gas composition and carbon gasification of crude glycerin using the reaction conditions of temperature and reactor residence time. To gain a better understanding of how the functional groups of different hydrocarbon molecules react when exposed to supercritical water, experiments were also conducted to determine the effect of hydroxyl groups on hydrocarbons in supercritical water. These experiments used isopropanol, propylene glycol, and glycerin as monohydric, dihydric, and trihydric alcohol feeds. The effect that the number and the position of hydroxyl groups in the molecular structures had on carbon gasification and gas composition were determined at multiple temperatures, of hydroxyl groups were shown to have a great impact on the decomposition mechanism of hydrocarbons"--Abstract, leaf iv
- Language
- eng
- Label
- The effect of supercritical water on crude glycerin solution
- Title
- The effect of supercritical water on crude glycerin solution
- Statement of responsibility
- by Jared Scott Bouquet
- Language
- eng
- Summary
- "Crude glycerin solution, a principal byproduct of the conventional biodiesel process, was reacted in supercritical water using a specially designed Haynes® Alloy 282 reactor system for the production of hydrogen rich syngas. The effects of temperature, pressure, water-to-carbon molar ratio, reactor residence time, and glycerin-to-methanol weight ratio on the extent of carbon gasification and gas composition were explored. Based on the results, the extent and selectivity of reactions that concurrently occur when methanol and glycerin are in the presence of supercritical water were analyzed. A decomposition reaction pathway for glycerin conversion to syngas was hypothesized, and then utilizing the results of the crude glycerin solution experiments, as well as experiments using pure methanol and pure glycerin with supercritical water, the hypothesized decomposition pathway was evaluated. Also an empirical equation was formulated to predict the gas composition and carbon gasification of crude glycerin using the reaction conditions of temperature and reactor residence time. To gain a better understanding of how the functional groups of different hydrocarbon molecules react when exposed to supercritical water, experiments were also conducted to determine the effect of hydroxyl groups on hydrocarbons in supercritical water. These experiments used isopropanol, propylene glycol, and glycerin as monohydric, dihydric, and trihydric alcohol feeds. The effect that the number and the position of hydroxyl groups in the molecular structures had on carbon gasification and gas composition were determined at multiple temperatures, of hydroxyl groups were shown to have a great impact on the decomposition mechanism of hydrocarbons"--Abstract, leaf iv
- Related
-
- Determination of a comprehensive mechanistic reaction pathway and the effects of reaction parameters on the decomposition of a crude glycerin solution in supercritical water
- MST thesis. Chemical Engineering (Ph.D., 2012)
- Roles of hydroxyl group in the supercritical water reaction of polyhdric alcohols
- Cataloging source
- UMR
- http://library.link/vocab/creatorDate
- 1987-
- http://library.link/vocab/creatorName
- Bouquet, Jared Scott
- Degree
- Ph. D.
- Dissertation year
- 2012.
- Granting institution
- Missouri University of Science and Technology
- Illustrations
- illustrations
- Index
- no index present
- Literary form
- non fiction
- Nature of contents
- theses
- http://library.link/vocab/subjectName
-
- Glycerin
- Supercritical fluids
- Synthetic fuels
- Label
- The effect of supercritical water on crude glycerin solution, by Jared Scott Bouquet
- Note
- Vita
- Bibliography note
- Includes bibliographical references (leaves 138-142)
- Carrier category
- volume
- Carrier category code
-
- nc
- Carrier MARC source
- rdacarrier
- Content category
- text
- Content type code
-
- txt
- Content type MARC source
- rdacontent
- Control code
- 815660308
- Dimensions
- 28 cm
- Extent
- xv, 143 leaves
- Media category
- unmediated
- Media MARC source
- rdamedia
- Media type code
-
- n
- Other physical details
- illustrations
- System control number
- (OCoLC)815660308
- Label
- The effect of supercritical water on crude glycerin solution, by Jared Scott Bouquet
- Note
- Vita
- Bibliography note
- Includes bibliographical references (leaves 138-142)
- Carrier category
- volume
- Carrier category code
-
- nc
- Carrier MARC source
- rdacarrier
- Content category
- text
- Content type code
-
- txt
- Content type MARC source
- rdacontent
- Control code
- 815660308
- Dimensions
- 28 cm
- Extent
- xv, 143 leaves
- Media category
- unmediated
- Media MARC source
- rdamedia
- Media type code
-
- n
- Other physical details
- illustrations
- System control number
- (OCoLC)815660308
Subject
Related
- Determination of a comprehensive mechanistic reaction pathway and the effects of reaction parameters on the decomposition of a crude glycerin solution in supercritical water
- MST thesis. Chemical Engineering (Ph.D., 2012)
- Roles of hydroxyl group in the supercritical water reaction of polyhdric alcohols
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<div class="citation" vocab="http://schema.org/"><i class="fa fa-external-link-square fa-fw"></i> Data from <span resource="http://link.library.mst.edu/portal/The-effect-of-supercritical-water-on-crude/q2QaKfZcdlA/" typeof="Book http://bibfra.me/vocab/lite/Item"><span property="name http://bibfra.me/vocab/lite/label"><a href="http://link.library.mst.edu/portal/The-effect-of-supercritical-water-on-crude/q2QaKfZcdlA/">The effect of supercritical water on crude glycerin solution, by Jared Scott Bouquet</a></span> - <span property="potentialAction" typeOf="OrganizeAction"><span property="agent" typeof="LibrarySystem http://library.link/vocab/LibrarySystem" resource="http://link.library.mst.edu/"><span property="name http://bibfra.me/vocab/lite/label"><a property="url" href="http://link.library.mst.edu/">Missouri University of Science & Technology Library</a></span></span></span></span></div>
