Glycerin reformation in high temperature and pressure water
Resource Information
The work Glycerin reformation in high temperature and pressure water represents a distinct intellectual or artistic creation found in Missouri University of Science & Technology Library. This resource is a combination of several types including: Work, Language Material, Books.
The Resource
Glycerin reformation in high temperature and pressure water
Resource Information
The work Glycerin reformation in high temperature and pressure water represents a distinct intellectual or artistic creation found in Missouri University of Science & Technology Library. This resource is a combination of several types including: Work, Language Material, Books.
- Label
- Glycerin reformation in high temperature and pressure water
- Statement of responsibility
- by Jason Wade Picou
- Language
- eng
- Summary
- "The noncatalytic reformation of glycerin in supercritical water was studied in a Haynes 282 tubular reactor. In order to determine which parameters were the most influential, a 23 experimental matrix was conducted, with temperatures of 500 and 700°C, water/glycerin molar ratios of 3:1 and 13:1, and residence times of 30 and 90 seconds, all at a pressure of 24 MPa. It was found that temperature had the largest effect on the two gasification parameters deemed most important, gasification percentage and hydrogen yield. Based on this, the effect of temperature was further investigated by looking at 50°C intervals from 500 to 800°C. From this it was determined that a temperature of 700 to 750°C was most conducive to glycerin reformation. The results were compared to equilibrium, as calculated by Gibbs free energy minimization. It was found that at temperatures from 750°C to 800°C; most of the results were at equilibrium. Based on this, kinetic models were developed for experiments not in equilibrium. The first model is a pseudo first order model of the gasification, which compares favorably with other studies. The second kinetic model takes into account the carbon containing gaseous species. Three reactions are used to model the gaseous products: Complete gasification of the glycerin into carbon monoxide and hydrogen, water gas shift of the resulting carbon monoxide, and a reaction in which glycerin and hydrogen combine to produce methane. Other reaction pathways were tested, and they either did not fit the data as well, or were thermodynamically impossible. The reactions are also capable of predicting hydrogen production for most conditions"--Abstract, p. iii
- Cataloging source
- UMR
- Degree
- Ph. D.
- Dissertation year
- 2012.
- Granting institution
- Missouri University of Science and Technology
- Illustrations
- illustrations
- Index
- no index present
- Literary form
- non fiction
- Nature of contents
-
- dictionaries
- theses
- Target audience
- specialized
Context
Context of Glycerin reformation in high temperature and pressure waterWork of
No resources found
No enriched resources found
Embed
Settings
Select options that apply then copy and paste the RDF/HTML data fragment to include in your application
Embed this data in a secure (HTTPS) page:
Layout options:
Include data citation:
<div class="citation" vocab="http://schema.org/"><i class="fa fa-external-link-square fa-fw"></i> Data from <span resource="http://link.library.mst.edu/resource/2ez8Pjctx4Q/" typeof="CreativeWork http://bibfra.me/vocab/lite/Work"><span property="name http://bibfra.me/vocab/lite/label"><a href="http://link.library.mst.edu/resource/2ez8Pjctx4Q/">Glycerin reformation in high temperature and pressure water</a></span> - <span property="potentialAction" typeOf="OrganizeAction"><span property="agent" typeof="LibrarySystem http://library.link/vocab/LibrarySystem" resource="http://link.library.mst.edu/"><span property="name http://bibfra.me/vocab/lite/label"><a property="url" href="http://link.library.mst.edu/">Missouri University of Science & Technology Library</a></span></span></span></span></div>
Note: Adjust the width and height settings defined in the RDF/HTML code fragment to best match your requirements
Preview
Cite Data - Experimental
Data Citation of the Work Glycerin reformation in high temperature and pressure water
Copy and paste the following RDF/HTML data fragment to cite this resource
<div class="citation" vocab="http://schema.org/"><i class="fa fa-external-link-square fa-fw"></i> Data from <span resource="http://link.library.mst.edu/resource/2ez8Pjctx4Q/" typeof="CreativeWork http://bibfra.me/vocab/lite/Work"><span property="name http://bibfra.me/vocab/lite/label"><a href="http://link.library.mst.edu/resource/2ez8Pjctx4Q/">Glycerin reformation in high temperature and pressure water</a></span> - <span property="potentialAction" typeOf="OrganizeAction"><span property="agent" typeof="LibrarySystem http://library.link/vocab/LibrarySystem" resource="http://link.library.mst.edu/"><span property="name http://bibfra.me/vocab/lite/label"><a property="url" href="http://link.library.mst.edu/">Missouri University of Science & Technology Library</a></span></span></span></span></div>
